Controlling the shapes of silver nanocrystals with different capping agents.

نویسندگان

  • Jie Zeng
  • Yiqun Zheng
  • Matthew Rycenga
  • Jing Tao
  • Zhi-Yuan Li
  • Qiang Zhang
  • Yimei Zhu
  • Younan Xia
چکیده

This paper provides direct evidence to support the role of a capping agent in controlling the evolution of Ag seeds into nanocrystals with different shapes. Starting with single-crystal seeds (spherical or cubic in shape), we could selectively obtain Ag octahedrons enclosed by {111} facets and nanocubes/nanobars enclosed by {100} facets by adding sodium citrate (Na(3)CA) and poly(vinyl pyrrolidone) (PVP), respectively, as a capping agent while all other parameters were kept the same. This research not only offers new insights into the role played by a capping agent in shape-controlled synthesis but also provides, for the first time, Ag octahedrons as small as 40 nm in edge length for optical and spectroscopic studies.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 132 25  شماره 

صفحات  -

تاریخ انتشار 2010